10423.液液萃取分離巰基乙酸水混合體系的研究

1、學(xué)位論文獨(dú)創(chuàng)性聲明本人鄭重聲明：所提交的學(xué)位論文是本人在導(dǎo)師指導(dǎo)下進(jìn)行的研究工作和取得的研究成果。本論文中除引文外，所有實(shí)驗(yàn)、數(shù)據(jù)和有關(guān)材料均是真實(shí)的。本論文中除引文和致謝的內(nèi)容外，不包含其他人或其它機(jī)構(gòu)已經(jīng)發(fā)表或撰寫過的研究成果。其他同志對(duì)本研究所做的貢獻(xiàn)均已在論文中作了聲明并表示了謝意。學(xué)位論文作者簽名：套豇日期：2口肜，莎，二占學(xué)位論文使用授權(quán)聲明研究生在校攻讀學(xué)位期間論文工作的知識(shí)產(chǎn)權(quán)單位屬南京師范大學(xué)。學(xué)校有權(quán)保存本學(xué)位論文的

2、電子和紙質(zhì)文檔，可以借閱或上網(wǎng)公布本學(xué)位論文的部分或全部內(nèi)容，可以采用影印、復(fù)印等手段保存、匯編本學(xué)位論文。學(xué)?？梢韵驀矣嘘P(guān)機(jī)關(guān)或機(jī)構(gòu)送交論文的電子和紙質(zhì)文檔，允許論文被查閱和借閱。(保密論文在解密后遵守此規(guī)定)保密論文注釋：本學(xué)位論文屬于保密論文，密級(jí)：——保密期限為——年。學(xué)位論文作者簽名：殄量日期：為，6多，≥多指導(dǎo)教師簽名日期：例，&Abs訂actAbstractTheapplications，productiontechno

3、bgyfutureprospectofIsooctylmercapto—acetateweresummarizedinthispaperTheproblemofsolventrecoveryduringthemanufactureofIsooctylalcohol，thatis，separatingthemixturesystemofMercaptoa—ceticAcidand姊留國￡wasanalyzedTheperformancea

4、ndapplicationsofMercaptoaceticAcidandwaterwereintroducedWhat’SmorethedifficultyinseparatingandpurifyingthemixturesystemofMercaptoaceticAcidandwaterwereanalyzedandtherecentmethodsofseparatingMercaptoaceticAcid舶mitssolutio

5、nwerereviewedinthepaperThenamethodofliquid—liquidextractionwasalsocarriedouttoseparateMercaptoaceticAcidfiomitssolutionAccordingtothegeneralprincipleofextracmntsselections，somenewresearchesandexperimentswerecarriedoutitt

6、urnedoutthatIsooctylalcoholcouldbechosenastherightextractingtoseparateMercaptoaceticAcidwatermixedsolutionEsterificationwasusedbetweenIsooctylalcoholandMercaptoaceticAcid，andthenisooctylthioglycohteandIsooctylalcoholwere

7、separatedComprehensiveutilizationofrenewableresourceswasachievedFurthertheextractioncapacityofisopropanolastheextractionagentwasana1yzedbysinglefactoranalysismethodDifferentinfluencingfactorsontheliq—uidliquidequilibrium

8、suchasstirringtime，stirringvelocityandsettingtimewerestudiedindetailonthebasicofwhichtheliquid—liquiddataweretestedTheinteracriveparametersofNRTLandUNIQUACequationwerecorrelated，thebasicU點(diǎn)dataweresknulatedTheresultsshowe

9、dthatNRTLequationwasmoresuitableOnthebasicofoptimalconditionexperimentsofcrossflowextractionwereconducted，consideringtheinfluencingfactorsofsolventratioandextractionprogres—sionTheresultsshowedthattheQualitycontentof1Mer

10、captoaceticAcidcouldbelessthanO50％bythreeextractionprogressionsattheratioS：F=I：IExperimentsofcountercurrentextractionwereSimulatedwithNRTLconsideringtheinfluencingfactorsofrawratioTheresultsshowedthatintheconditionof4the

11、oreticalseries，theQualitycontentofMercaptoaceticAcidwas0。42％attheratioSf=1：1ComparedwithcountercurrentextractiontheresultsofcrossflowextractionwasbetterFinally，theQualitycontentofMercaptoaceticAcidInthecaffeinatephasecou